Repository: Freie Universit├Ąt Berlin, Math Department

Initial-state dependence of coupled electronic and nuclear fluxes in molecules

Kenfack, A. and Marquardt, F. and Paramonov, G. K. and Barth, I. and Lasser, C. and Paulus, B. (2010) Initial-state dependence of coupled electronic and nuclear fluxes in molecules. Phys. Rev. A, 81 (5). 052502.

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Official URL: http://dx.doi.org/10.1103/PhysRevA.81.052502

Abstract

We demonstrate that coupled electronic and nuclear fluxes in molecules can strongly depend on the initial state preparation. Starting the dynamics of an aligned D2 + molecule at two different initial conditions, the inner and the outer turning points, we observe qualitatively different oscillation patterns of the nuclear fluxes developing after 30 fs. This corresponds to different orders of magnitude bridged by the time evolution of the nuclear dispersion. Moreover, there are attosecond time intervals within which the electronic fluxes do not adapt to the nuclei motion depending on the initial state. These results are inferred from two different approaches for the numerical flux simulation, which are both in good agreement.

Item Type:Article
Subjects:Physical Sciences > Chemistry > Physical Chemistry
Mathematical and Computer Sciences > Mathematics > Mathematical Modelling
Physical Sciences > Physics > Chemical Physics
ID Code:922
Deposited By: Burkhard Schmidt
Deposited On:03 Aug 2010 08:33
Last Modified:03 Mar 2017 14:40

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