Repository: Freie Universit├Ąt Berlin, Math Department

Librational control of photochemical reactions in small clusters

Jungwirth, P. and Zdanska, P. and Schmidt, B. (1998) Librational control of photochemical reactions in small clusters. J. Phys. Chem. A, 102 (37). pp. 7241-7244.

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Official URL: http://dx.doi.org/10.1021/jp982135l

Abstract

A novel approach to the control of photochemical reaction yield in hydrogen containing clusters is outlined and applied to the process of the Cl2 molecule formation from a UV photolyzed Cl...HCl species. The control mechanism consists in a far-IR preexcitation of the large amplitude hydrogenic bending (librational) mode prior to the HCl photodissociation, leading to more than a factor of two enhancement of the Cl2 yield both in the parent and deuterated cluster.

Item Type:Article
Subjects:Physical Sciences > Physics > Mathematical & Theoretical Physics > Computational Physics
Physical Sciences > Chemistry > Physical Chemistry
Physical Sciences > Physics > Chemical Physics
ID Code:853
Deposited By: Burkhard Schmidt
Deposited On:15 Mar 2010 08:44
Last Modified:03 Mar 2017 14:40

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