Jungwirth, P. and Zdanska, P. and Schmidt, B. (1998) Librational control of photochemical reactions in small clusters. J. Phys. Chem. A, 102 (37). pp. 7241-7244.
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Official URL: http://dx.doi.org/10.1021/jp982135l
Abstract
A novel approach to the control of photochemical reaction yield in hydrogen containing clusters is outlined and applied to the process of the Cl2 molecule formation from a UV photolyzed Cl...HCl species. The control mechanism consists in a far-IR preexcitation of the large amplitude hydrogenic bending (librational) mode prior to the HCl photodissociation, leading to more than a factor of two enhancement of the Cl2 yield both in the parent and deuterated cluster.
| Item Type: | Article |
|---|---|
| Subjects: | Physical Sciences > Physics > Mathematical & Theoretical Physics > Computational Physics Physical Sciences > Chemistry > Physical Chemistry Physical Sciences > Physics > Chemical Physics |
| ID Code: | 853 |
| Deposited By: | Burkhard Schmidt |
| Deposited On: | 15 Mar 2010 08:44 |
| Last Modified: | 03 Mar 2017 14:40 |
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